Test Kitchen tip: Natural vs. Dutch-process cocoa powder ... and a recipe (2024)

Like chocolate, cocoa powder is made from cacao beans. After the beans are processed into a paste known as chocolate liqueur, some of the cocoa butter is removed and the remaining solids are pulverized into a powder.

Standard “natural” (or non-alkalized) cocoa powder is typically sold unsweetened, and although it may taste rather bitter and harsh on its own, its natural acidity works with baking soda to help leaven baked goods, giving a finished dish a balanced chocolate flavor.

Cocoa powder is often treated with an alkali to make what is known as Dutch-process or alkalized cocoa. The alkali helps neutralize the natural acidity of the powder, giving the cocoa a more mellow and smooth, less bitter flavor.

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Because of this, Dutch-process cocoa is often preferred when “dusting” or garnishing a finished cake or desserts; in baking, it’s used in recipes that call primarily for baking powder as a leavener. It can also have a richer, deeper color than natural cocoa.

When baking, keep in mind that natural and Dutch-process cocoa powders are not always interchangeable -- blindly substituting one for the other can upset the delicate chemical balance in a recipe, spoiling results and flavor (you don’t want your chocolate cake to taste like it was made with soap). Sometimes one cocoa powder can be substituted for the other in recipes. According to “The King Arthur Flour Baker’s Companion”:

“If a recipe calls for natural cocoa and baking soda and you want to use Dutch-process cocoa, substitute an equal amount of Dutch-process cocoa but replace the soda with twice the amount of baking powder. If the recipe calls for Dutch-process cocoa powder and baking powder, substitute the same amount of natural cocoa but replace the baking powder with half the amount of baking soda.”

Cooking is fun — at least it should be! No matter how long you’ve been in the kitchen, there is always something new to learn, whether it’s a simple twist on an old technique, or a handy tip to save time and energy. In this series of short videos, I demonstrate a variety of kitchen tips, including how to hold a chef’s knife for maximum control and how to use a spoon to peel fresh ginger. If you have any gadgets, kitchen tips or questions you’d like me to explore, leave a comment or shoot me an email at noelle.carter@latimes.

MILK’S OOEY-GOOEY DOUBLE-CHOCOLATE COOKIES

Total time: 40 minutes, plus 1 hour chilling time for the batter | Makes 1 1/2 dozen

Note: Adapted from Bret Thompson of Milk in Los Angeles

1/4 pound (4 ounces) unsweetened chocolate
4 tablespoons ( 1/2 stick) butter
3 eggs
2 teaspoons vanilla extract
1 cup sugar
1/2 cup flour
2 tablespoons Dutch-process cocoa powder
1/2 teaspoon baking powder
1/2 teaspoon salt
1 pound bittersweet chocolate (chunks or chips)

1. In a bowl set over a pot of simmering water, melt the unsweetened chocolate and butter. Remove from the heat and cool slightly.

2. In the bowl of a mixer with a paddle attachment, or in a large bowl using a fork, combine the eggs, vanilla and sugar. Mix just until incorporated and set aside.

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3. Sift together the flour, cocoa powder, baking powder and salt into a medium bowl. Set aside.

4. Add the melted chocolate to the egg mixture and mix just until combined. Stir in the sifted dry ingredients and mix just until combined, then stir in the bittersweet chocolate.

5. Cover the batter with plastic wrap and refrigerate for at least 1 hour to chill thoroughly. Heat the oven to 350 degrees.

6. Divide the dough into 18 portions. Grease your hands (to prevent the dough from sticking) and shape the portions into balls. Place the balls on a greased, parchment-lined sheet pan, leaving 2 to 3 inches between each.

7. Bake until the edges of the cookies are just set and the center is still soft, 10 to 12 minutes, rotating the pan halfway through. Place the cookies, still on the parchment, on a rack and cool completely before serving. They will be very soft.

Each cookie: 251 calories; 4 grams protein; 29 grams carbohydrates; 3 grams fiber; 18 grams fat; 9 grams saturated fat; 42 mg. cholesterol; 92 mg. sodium.

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Test Kitchen tip: Natural vs. Dutch-process cocoa powder ... and a recipe (2024)

FAQs

What is the difference between Dutch-processed and natural cocoa powder? ›

Dutch process cocoa has a more intense "chocolatey" flavor while natural cocoa looks lighter in color and tastes slightly astringent. But since you're not dealing with any chemical leaveners, your choice of cocoa won't have much impact on the dessert's texture.

How do I substitute Dutch process cocoa for natural? ›

Obviously, it's best to use whichever cocoa your recipe calls for. But can you substitute natural cocoa for Dutch-process (or vice-versa) in a pinch? Yes, you can obtain decent results simply by substituting one cocoa for another without making any adjustments.

How do you tell if a product contains Dutch process cocoa? ›

Different names for the same thing – however, always check the ingredient label when purchasing or using cocoa powder because some packaging is not always clear. Any ingredient mention of “alkali” or “Dutch” means it's Dutch-processed and not natural. If it's natural, the ingredient should simply be “cocoa.”

Is natural or Dutch processed cocoa powder better for brownies? ›

You can use either type in recipes that do not call for baking soda or baking powder. Such as sauces, hot cocoa, brownies (as long as there is not BP or BS!), frostings, ice cream, pudding, etc. There is no leavening occurring, so it doesn't matter. You can go by your taste preference.

When not to use Dutch process cocoa? ›

Recipes that use baking soda typically use natural cocoa powder, because baking soda needs an acid to do its job. In this scenario, you typically cannot substitute Dutch process for natural cocoa, as the recipe likely relies on an acidic natural cocoa powder for proper rise and flavor.

What is the best cocoa powder for baking? ›

“When it comes to baking, I prefer Dutch process cocoa powder,” says former BA food editor Claire Saffitz. “The alkalizing process darkens the color and typically deepens the flavor.” Dutch process cocoa powder produces baked goods that taste more intensely chocolatey.

Is Hershey's baking cocoa Dutch processed? ›

Fry's Cocoa is an example of Dutch processed cocoa. In contrast, a non alkalized cocoa, such as Hershey's, is also unsweetened, but because it has not been Dutch processed, it still contains cocoa's natural acids. Non alkalized, or natural cocoa tends to be lighter in color but less mellow in flavor.

Does cocoa powder expire? ›

Your cocoa powder will have a 'best-before' date on it. The taste might start to gradually mellow after that date or it might go a bit 'clumpy', but it's unlikely you'll notice much difference. It's still safe to eat as long as it doesn't feel moist or smell unpleasant.

How to test cocoa powder? ›

Here are some important aspects of sensory testing of cocoa: Taste: Cocoa has a rich and complex taste that can vary depending on the variety of cocoa and the region where it is grown. Typical flavors in cacao include chocolate, nut, caramel, fruit and spice.

What brand of cocoa is not Dutch-processed? ›

Hershey's, Nestle and Ghirardelli are all natural cocoa powders.

How can you tell if cocoa powder is pure? ›

“Natural” signifies that it is unprocessed beyond the initial separating from the cocoa butter and grinding into a powder; it is also sometimes labeled on packaging as “unsweetened cocoa powder” or “pure cocoa powder.” It is fruity, complex, and bitter in flavor, and light brown in color.

What is the best cocoa powder to use for chocolate cake? ›

Dutch-Processed Cocoa Powder

It makes amazingly rich, dark, and tender cakes, fudgy, moist brownies and cookies, and incredibly luscious frosting.

Which cocoa powder is best for brownies? ›

Unsweetened cocoa powder (aka natural cocoa powder) will yield a brownie with a lighter color and less intense flavor.

Is it better to use cocoa powder or melted chocolate in brownies? ›

And where melted chocolate introduces more moisture to the brownie and, consequently, requires additional flour to balance it out, cocoa powder can stand in for a portion of the flour. With less flour, the brownies taste barely bound, with no risk of cakiness or toughness.

Is Dutch processed cocoa healthier? ›

Alkali-processed cocoa, commonly known as dutched cocoa, is not as healthy as regular cocoa powder. Dutched cocoa can have as little as half the phytonutrients of regular cocoa, but that just means you have to use twice as much to get a rich, chocolatey flavor.

Is Nestle cocoa powder natural or dutch processed? ›

A word of caution about finding natural cocoa powder. Some cocoa may not be labeled natural, but rather unsweetened or baking cocoa. Hershey's, Nestle and Ghirardelli are all natural cocoa powders.

Why is Dutch processed cocoa so expensive? ›

But because Dutch-style cocoa is perceived as a specialty product that can be sold at a higher price, most Dutch-cocoa brands contain nearly twice the fat of natural styles, and often come from better-quality beans.

What is the difference between natural and alkalized cocoa powder? ›

Alkalized cocoa powder is fluffier, and has a deeper colour and a more palatable taste than natural cocoa. Both types of cocoa powder have distinct flavour profiles and niche uses in the culinary world.

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